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101.
Pollen analysis at two sites, correlated by the presence of the 190,000 yr-old Sheep Creek tephra, documents fluctuations in vegetation and climate consistent with this date and indicates that the records span marine oxygen isotope stage 7 and the stage 6/7 transition. Dawson Cut, near Fairbanks, Alaska, provides a 5.2-m-long pollen record of interglacial boreal forest succeeded by shrub tundra and then forest/tundra. Ash Bend, Stewart River, central Yukon, provides a 9.5-m-long record of interglacial boreal forest succeeded by forest/tundra, shrub tundra, and herbaceous tundra. The replacement of forest at both sites by more open or tundra vegetation indicates warm interglacial conditions giving way to cold and arid climate. It is not clear whether stage 7 was warmer than the present. The warm-cool-warm climate oscillation evident at both sites may correlate to Lake Baikal substages 7a, 7b, and 7c. Sheep Creek tephra fell on forest/tundra vegetation.  相似文献   
102.
In-situ Formation of Light-Absorbing Organic Matter in Cloud Water   总被引:1,自引:0,他引:1  
Current climate models seem to underestimate the flux of solar energy absorbed by the global troposphere. All of these models are constrained with the assumption that cloud droplets consist of pure water. Here we demonstrate in a simple laboratory experiment that aromatic hydroxy-acids which are found in continental fine aerosol can react with hydroxyl radicals under typical conditions prevalent in cloud water influenced by biomass burning. The reactions yield colored organic species which do absorb solar radiation. We also suggest that the products of such reactions may be humic-like substances whose presence in continental aerosol has been confirmed but their source mechanisms are still much sought after. We also attempt to give a first order estimate of the enhancement of water absorption at a visible wavelength under atmospheric conditions.  相似文献   
103.
This work presents the temporal evolution and spatial distribution of nitrogen dioxide (NO2) measured with the help of passive diffusion tubes in different environments: rural, sub-urban, urban, at La Réunion Island in December 1997 and November 2000 (austral spring), respectively. NO2 concentration exhibits notable enhancement from 1997 to 2000. For instance, its mean concentration was 16 and 20 μg/m3 in December 1997 and November 2000, respectively, at La Réunion Island, especially in inhabited regions due to increase of local anthropogenic activities, mainly traffic circulation, in the absence of house heating and biomass burning. We also observe a net increase of pollutant levels by a factor two in rural/remote areas within 3 years, which is tied to the extension of inhabited areas and air-flows from enhanced local sources. The increase of atmospheric pollutants is mainly due to enhancement of anthropogenic activities (traffic) since the 1990s at La Réunion Island, which results from a constant increase of population and consequently, from a higher number of vehicles in circulation. Importantly, in cities like Saint-Denis, where traffic network has been subject to notable improvement (e.g. single to double lanes, etc.), pollutant levels exhibit little variability as in temperate continental latitudes. Semi-continuous NO2 concentration measured in parallel with ozone in November 2000 also showed that daytime photochemical ozone production is influenced by pollutant and precursor (NO2) levels at Saint-Denis, while nighttime ozone increase is mainly tied to dynamical processes. The November 2000 ozone diurnal pattern is notably different from that observed in September 1995, during which a daytime ozone loss was observed, pointing out that atmospheric conditions have been subject to notable changes, i.e., clean to moderately polluted, within a few years at La Réunion Island. The results presented here point out that the ‘source enhancement effect’ is superimposed on dynamical and photochemical processes to influence pollutants variability and hence atmospheric chemistry, in a quite ‘pristine’ tropical oceanic region.  相似文献   
104.
矿物流体包裹体中的羧酸曾贻善刘家齐(北京大学地质系,北京100871)(地矿部宜昌地质矿产研究所,宜昌443003)关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团(—COOH)的物质称为羧酸。Fein[1]和Shock[2]曾概述羧酸在自...  相似文献   
105.
沉积盆地流体—岩石相互作用研究的现状   总被引:17,自引:0,他引:17  
沉积盆地流体-岩石相互作用研究主要是通过实验地球化学和岩石学,地球化学模拟方法开展的,综述了这一领域的研究现状,主要包括有机酸来源和分布及期 对矿物稳定性的影响,地层水成因与演化、烃类与岩石间的氧化还原反应、以及储层润湿性的变化等,并展望了其 发展趋势。  相似文献   
106.
It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.  相似文献   
107.
 Marine contamination of groundwater may be caused by seawater intrusion and by salt spray. The role of both processes was studied in the Cyclades archipelago on four small islands (45–195 km2) whose aquifers consist essentially of fractured, weathered metamorphic rocks. Annual rainfall ranges from 400 to 650 mm and precipitation has high total dissolved solids contents of 45–223 mg l–1. The chemical characteristics of the groundwater, whose salinity is from 0.4 to 22 g l–1, are strongly influenced by seawater intrusion. However, the effect of atmospheric input is shown in certain water sampling locations on high ground elevation where the dissolved chloride contents may attain 200 mg l–1. Received: 14 November 1995 · Accepted: 9 September 1996  相似文献   
108.
中国海洋地球物理进展   总被引:2,自引:2,他引:2       下载免费PDF全文
在中国地球物理学会50周年之际,总结海洋地球物理工作是十分重要的文章从中国海油气普查、近海工程地质调查。大洋多金属结核调查和中国海基础调查四个方面简要地阐述它们的进展。  相似文献   
109.
电法勘探的发展和展望   总被引:9,自引:1,他引:9       下载免费PDF全文
何继善 《地球物理学报》1997,40(Z1):308-316
电法勘探在经历了近一个世纪的发展后,其方法理论、仪器设备、野外数据采集、处理和解释等方面都经历了一系列重大变化.本文以方法理论的进展为主线,回顾、展望了目前电法勘探中几个重要而令人关注的研究焦点.这些问题的研究进展将会对21世纪的电法勘探产生深远的影响.  相似文献   
110.
南方地质条件有四方面的特点:碳酸盐岩区与特提斯域有关,具有良好的含油气前景;叠置在碳酸盐岩区上的南、北两大前陆盆地带,对古生界原型盆地烃源岩的演化、油气藏形成和保存起到重要作用;南方海相地层具有丰富的烃源岩;后期多旋回构造运动,使南方海相油气系统变得十分复杂。南方油气选区评价的关键是保存条件,在含油气系统中“保存单元”是优选勘探目标的重要依据。“九五”期间,一要主攻中、下扬子区,获重大突破;二要积极做好滇黔桂地区三个盆地(南盘江盆地、楚雄盆地、十万大山盆地)的预探;三要进一步搞好区域评价。  相似文献   
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